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The normal boiling point of bromine is 58.8 \circ C. Given that the vapor pressure of bromine is 75.0 torr at 2.5 \circ C, calculate the molar enthalpy of vaporization of bromine.


A) 2.90 kJ/mol
B) 3.57 kJ/mol
C) 3.76 kJ/mol
D) 29.7 kJ/mol
E) 31.3 kJ/mol

F) None of the above
G) A) and C)

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An example of a covalent network solid is


A) diamond.
B) potassium.
C) iodine.
D) sodium chloride.
E) none of these.

F) A) and B)
G) A) and C)

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NH3 has a higher boiling point than CH4.

A) True
B) False

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At a given temperature CCl4 has a weaker surface tension than H2O.

A) True
B) False

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The molar enthalpy of vaporization of boron tribromide is 30.5 kJ/mol, and its normal boiling point is 91 \circ C. What is the vapor pressure of BBr3 at 20 \circ C


A) 11.5 torr
B) 311 torr
C) 5.31 torr
D) 143 torr
E) 66.1 torr

F) C) and D)
G) A) and C)

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Butter melts over a range of temperatures, rather than with a sharp melting point. Butter is classified as a/an


A) metallic crystal.
B) covalent solid.
C) molecular crystal.
D) amorphous solid.
E) ionic crystal.

F) A) and E)
G) A) and D)

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The gas phase exists at the point labeled a. The gas phase exists at the point labeled a.

A) True
B) False

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Ethanol (C2H5 - OH) will have a greater viscosity than ethylene glycol (HO - CH2CH2 - OH) at the same temperature.

A) True
B) False

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The number of nearest neighbors (atoms that make contact) around each atom in a face-centered cubic lattice of a metal is


A) 2.
B) 4.
C) 6.
D) 8.
E) 12.

F) B) and D)
G) A) and D)

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Palladium crystallizes in a face-centered cubic unit cell. Its density is 12.0 g/cm3 at 27 \circ C. Calculate the atomic radius of Pd.


A) 154 pm
B) 138 pm
C) 1.95 * 10-8 nm
D) 0.109 nm
E) 1.95 * 10-8 cm

F) A) and C)
G) C) and E)

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Given the following liquids and their boiling points, which has the highest vapor pressure at its normal boiling point


A) ethanol, bp = 78 \circ C
B) methanol, bp = 65 \circ C
C) water, bp = 100 \circ C
D) benzene, bp = 80 \circ C
E) The vapor pressure of each of the liquids at its normal boiling point would be the same.

F) A) and C)
G) A) and E)

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Which one of the following substances will have both dispersion forces and dipole-dipole forces


A) HCl
B) BCl3
C) Br2
D) H2
E) CO2

F) D) and E)
G) A) and D)

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H2S has stronger intermolecular forces of attraction than H2Se.

A) True
B) False

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The structural form of the element Ge closely resembles the structure of


A) C (diamond) .
B) N (diatomic) .
C) As (tetrahedral) .
D) S (S8 ring) .
E) Kr (monatomic) .

F) All of the above
G) D) and E)

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The intermolecular forces present in C6H6 include which of the following I. dipole-dipole II. ion-dipole III. dispersion IV. hydrogen bonding


A) I, II, III, and IV
B) I and III
C) I, III, and IV
D) I and II
E) III only

F) B) and C)
G) A) and B)

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Indicate all the types of intermolecular forces of attraction in CH3OH(l) .


A) Dispersion and Dipole-dipole
B) Dipole-dipole and Ionic
C) Ion-dipole and Hydrogen bonding
D) Hydrogen bonding and Dispersion
E) Dispersion

F) None of the above
G) C) and D)

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Use the graph of vapor pressure to determine the normal boiling point of O2. Use the graph of vapor pressure to determine the normal boiling point of O<sub>2</sub>.    A)  84 K B)  88 K C)  90 K D)  92 K E)  O<sub>2</sub> doesn't boil because it is always a gas.


A) 84 K
B) 88 K
C) 90 K
D) 92 K
E) O2 doesn't boil because it is always a gas.

F) A) and C)
G) C) and D)

Correct Answer

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The shape of the water-to-glass meniscus results from the strong adhesive forces between glass and water.

A) True
B) False

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Which of the following phase changes is endothermic


A) Sublimation
B) Condensation
C) Freezing
D) Deposition

E) None of the above
F) A) and B)

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At room temperature, honey is more viscous than mustard.

A) True
B) False

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