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Solid iodine has a vapor pressure of 1.0 mmHg at 39 \circ C. How many moles of iodine will sublime into a 500 mL flask at this temperature If the volume of the flask is doubled at constant temperature, what will happen to the equilibrium vapor pressure of I2 (Assume some solid I2 is always present in the container.)


A) 2.1 * 10-4 mol; vapor pressure increases
B) 2.0 * 10-2 mol; vapor pressure increases
C) 2.6 * 10-5 mol; no change in vapor pressure
D) 2.1 * 10-4 mol; no change in vapor pressure
E) 2.6 * 10-5 mol; vapor pressure decreases

F) C) and D)
G) None of the above

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Use the graph of vapor pressure to determine the normal boiling point of CHCl3.  Use the graph of vapor pressure to determine the normal boiling point of CHCl<sub>3</sub>.   A)  19<sup> \circ </sup>C B)  52<sup> \circ </sup>C C)  60<sup> \circ </sup>C D)  64<sup> \circ </sup>C E)  70<sup> \circ </sup>C


A) 19 \circ C
B) 52 \circ C
C) 60 \circ C
D) 64 \circ C
E) 70 \circ C

F) D) and E)
G) None of the above

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Which one of the following substances should exhibit hydrogen bonding in the liquid state


A) SiH4
B) H2
C) H2S
D) CH4
E) CH3NH2

F) A) and D)
G) A) and C)

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How much energy (heat) is required to convert 25.5 g of H2O(l) at 35.0 \circ C to H2O(g) at 115.0 \circ C specific heat of ice: 2.09 J/gCΔHfus=6.02 kJ/mol \quad 2.09 \mathrm{~J} / \mathrm{g} \cdot{ }^{\circ} \mathrm{C} \quad \Delta \mathrm{H}_{\mathrm{fus}}=6.02 \mathrm{~kJ} / \mathrm{mol} specific heat of water: 4.18 J/gCΔHvap=40.7 kJ/mo 4.18 \mathrm{~J} / \mathrm{g}{ \cdot}^{\circ} \mathrm{C} \quad \Delta \mathrm{H}_{\mathrm{vap}}=40.7 \mathrm{~kJ} / \mathrm{mo} . specific hast of steam: 1.84 J/gC 1.84 \mathrm{~J} / \mathrm{g} \cdot{ }^{\circ} \mathrm{C}


A) 207 J
B) 7,630 J
C) 8,530 J
D) 9,130 J
E) 65,200 J

F) A) and D)
G) None of the above

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Which one of the following substances is expected to have the highest boiling point


A) HBr
B) HCl
C) HF
D) HI

E) A) and D)
F) A) and C)

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C8H18 has a higher vapor pressure than C4H10.

A) True
B) False

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CH4 has a higher boiling point than CH3OH.

A) True
B) False

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NH3 has a higher boiling point than PH3.

A) True
B) False

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Vanadium crystallizes in a body-centered cubic lattice, and the length of the edge of a unit cell is 305 pm. What is the density of V


A) 5.96 * 10-30 g/cm3
B) 2.98 * 10-6 g/cm3
C) 2.98 g/cm3
D) 5.96 g/cm3
E) 11.9 g/cm3

F) A) and C)
G) D) and E)

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Platinum has a face-centered cubic crystal structure and a density of 21.5 g/cm3. What is the radius of the platinum atom


A) 69 pm
B) 98 pm
C) 139 pm
D) 196 pm
E) 277 pm

F) D) and E)
G) A) and E)

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Which of the following liquids would have the lowest viscosity at 25 \circ C  Which of the following liquids would have the lowest viscosity at 25<sup> \circ </sup>C   A)  A B)  B C)  C D)  D E)  E


A) A
B) B
C) C
D) D
E) E

F) A) and D)
G) B) and E)

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Find the temperature at which ethanol boils on a day in the mountains when the barometric pressure is 547 mmHg. (Given: The heat of vaporization of ethanol is 39.3 kJ/mol; the normal boiling point of ethanol is 78.3 \circ C.)


A) 10.0 \circ C
B) 69.9 \circ C
C) 74.6 \circ C
D) 76.5 \circ C
E) 77.9 \circ C

F) C) and E)
G) A) and D)

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Octane, C8H18, boils at 125 \circ C as compared to water, which boils at 100 \circ C. This information suggests that the dispersion forces in nonpolar octane molecules are stronger than dispersion forces and hydrogen bonding in water.

A) True
B) False

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C(CH3)4 has a higher vapor pressure than CH3CH2CH2CH2CH3.

A) True
B) False

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The freezing point of a liquid does not change as the atmospheric pressure changes.

A) True
B) False

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Acetic acid has a heat of fusion of 10.8 kJ/mol and a heat of vaporization of 24.3 kJ/mol. What is the expected value for the heat of sublimation of acetic acid


A) 35.1 kJ/mol
B) -13.5 kJ/mol
C) +13.5 kJ/mol
D) -35.1 kJ/mol
E) Not enough information is given to answer the question.

F) A) and E)
G) A) and B)

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Find the temperature at which water boils on a day in the mountains when the barometric pressure is 593 mmHg. (Given: the heat of vaporization of water is 40.79 kJ/mol)


A) 41.5 \circ C
B) 68.1 \circ C
C) 93.1 \circ C
D) 97.0 \circ C
E) 117 \circ C

F) A) and E)
G) A) and B)

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HOCH2CH2OH(s) is classified as a/an


A) metallic crystal.
B) covalent solid.
C) molecular crystal.
D) amorphous solid.
E) ionic crystal.

F) C) and D)
G) A) and E)

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3.59 g of water was introduced into an evacuated 1.50 L flask at 30 \circ C. What mass of water will evaporate (Vapor pressure of water at 30 \circ C is 31.82 mmHg.)


A) 2.52 * 10-3 g
B) 0.04187 g
C) 0.0455g
D) 0.4187 g
E) 0.455 g

F) C) and E)
G) B) and D)

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Which of the following constants is/are needed to calculate the amount of energy required to heat 30.5g of H2O(s) at -25.0 \circ C to H2O(l) at 55.0 \circ C I. Δ\Delta Hfus (H2O) II. Δ\Delta Hvap (H2O) III. specific heat of H2O(s) IV. specific heat of H2O(l) V. specific heat of H2O(g)


A) I, II, III, IV, and IV
B) I, III, and IV
C) III and IV
D) I only
E) I, II, III, and IV

F) A) and D)
G) A) and C)

Correct Answer

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